There are certainly many, not just one. Let me give you some examples linked to the quality or trait you might be looking for:
Best lead-in questions
Can you tell me about yourself?
This is always a good introductory question. Ask and then don’t say another thing until they are done. What they actually say is not critical, but how they answer this question is.
Do they focus on personal or professional details? How do they see themselves? Does this view fit into the culture of the company?